205108-17-4

Basic information

• Product Name: Benzene, 1-(1,2-butadienyl)-4-fluoro- (9CI)
• Synonyms: Benzene, 1-(1,2-butadienyl)-4-fluoro- (9CI)
• CAS NO: 205108-17-4
• Molecular Formula: C10H9F
• Molecular Weight: 148.1768632
• Product Categories: HALIDE
• Mol File: 205108-17-4.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzene, 1-(1,2-butadienyl)-4-fluoro- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(1,2-butadienyl)-4-fluoro- (9CI)(205108-17-4)
• EPA Substance Registry System: Benzene, 1-(1,2-butadienyl)-4-fluoro- (9CI)(205108-17-4)

Safety Data

• Hazardous Substances Data: 205108-17-4(Hazardous Substances Data)

Upstream product

• 1765-93-1 4-fluoroboronic acid 

Relevant articles and documents

Enantioselective, Stereodivergent Hydroazidation and Hydroamination of Allenes Catalyzed by Acyclic Diaminocarbene (ADC) Gold(I) Complexes

The gold-catalyzed enantioselective hydroazidation and hydroamination reactions of allenes are presented herein. ADC gold(I) catalysts derived from BINAM were critical for achieving high levels of enantioselectivity in both transformations. The sense of enantioinduction is reversed for the two different nucleophiles, allowing access to both enantiomers of the corresponding allylic amines using the same catalyst enantiomer. Chiral allylic azides and amines are obtained by enantioselective hydroazidation and hydroamination of allenes catalyzed by acyclic diaminocarbene gold(I) catalysts derived from BINAM. The sense of enantioinduction is reversed for the two different nucleophiles, allowing easy access to both enantiomers with a single catalyst enantiomer.