20511-20-0Relevant articles and documents
Heck reactions in a non-aqueous ionic liquid using silica supported palladium complex catalysts
Okubo, Keisuke,Shirai, Masayuki,Yokoyama, Chiaki
, p. 7115 - 7118 (2002)
The Heck reaction of iodobenzene and 4-methyl-iodobenzene with olefins using silica-supported palladium complex catalysts was conducted in 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim]PF6), exhibiting higher activities than in DMF in addition to easy product isolation and catalyst recycling.
Photoinduced Regioselective Olefination of Arenes at Proximal and Distal Sites
Ali, Wajid,Anjana, S. S.,Bhattacharya, Trisha,Chandrashekar, Hediyala B.,Goswami, Nupur,Guin, Srimanta,Maiti, Debabrata,Panda, Sanjib,Prakash, Gaurav,Saha, Argha,Sasmal, Sheuli,Sinha, Soumya Kumar
supporting information, p. 1929 - 1940 (2022/02/01)
The Fujiwara-Moritani reaction has had a profound contribution in the emergence of contemporary C-H activation protocols. Despite the applicability of the traditional approach in different fields, the associated reactivity and regioselectivity issues had
A New Nitrogen Pd(II) Complex Immobilized on Magnetic Mesoporous Silica: A Retrievable Catalyst for C–C Bond Formation
Mousavi, Samira,Mansoori, Yagoub,Nuri, Ayat,Koohi-Zargar, Behzad
, p. 1923 - 1936 (2020/11/30)
Abstract: A new nitrogen ligand, i.e. 1,3-di-(o-aminophenoxy)-2-propyl propargyl ether (DPPE), has been synthesized and characterized. Magnetic mesoporous silica composite (MNP@SiO2-SBA) was obtained via embedding magnetite nano-particles (MNPs) between SBA-15 channels. DPPE palladium dichloride (MNP@SiO2-SBA-DPPE-Pd(II)) was then prepared via click chemistry and fully characterized. The activity and recyclability of supported magnetic Pd(II) catalyst were evaluated in Heck coupling reaction after optimizing the optimal reaction conditions including solvent, amount of catalyst, base and temperature. Aryl iodides and aryl bromides showed enhanced activity compared to those of aryl chlorides in the Heck reaction. The catalyst was easily separated magnetically, reused in five runs sequentially, and no significant loss of activity was observed. Graphic Abstract: [Figure not available: see fulltext.]
Bimetallic nano alloy architecture on a special polymer: Ni or Cu merged with Pd for the promotion of the Mizoroki–Heck reaction and the Suzuki–Miyaura coupling
Patil, Vijay P,Kashid, Abhijit A,Solanki, Bhanupratap S,Kharul, Ulhas K,Iyer, Suresh
, (2021/02/12)
Abstract: Novel Ni-Pd and Cu-Pd bimetallic nano alloys was designed and heterogenized on the highly robust ABPBI [poly(2,5-benzimidazole)] polymer in high yields using NaBH4 as reducing agent. These were versatile ligand free catalysts for the Mizoroki–Heck reaction and Suzuki–Miyaura coupling. The bimetallic Ni-Pd-ABPBI catalyst for the Mizoroki–Heck reaction of 4-iodo anisole could be recycled 5 times with high yields. Aryl bromides could also be activated for the Mizoroki–Heck reaction using Cu-Pd-ABPBI NP catalysts, with moderate yields. Graphic abstract: Synopsis Novel bimetallic Ni-Pd and Cu-Pd nano alloys, heterogenized on the robust ABPBI [poly(2,5-benzimidazole)] polymer using NaBH4 as reducing agent, is described. These were versatile ligand free, noble metal conservative catalysts, for the Mizoroki–Heck reaction and the Suzuki–Miyaura coupling. Aryl bromides were activated for the Mizoroki–Heck reaction using the Cu-Pd-ABPBI catalyst.[Figure not available: see fulltext.]