205172-89-0Relevant academic research and scientific papers
A silver(I) center solely bonded to four gold(I) atoms
Contel, Maria,Garrido, Julian,Gimeno, M. Concepcion,Laguna, Mariano
, p. 1083 - 1084 (2007/10/03)
(Trimethylsilylmethyl)gold(I) complexes [{Au(CH2SiMe3)}2-(μ-P-P)] (P-P = dppm or dppe) reacted with silver derivatives (AgOClO3 or AgOSO2CF3) affording trinuclear [Au2Ag(CH2SiMe3)2(μ-P-P)A] (A = OClO3 or OSO2CF3) or pentanuclear [Au4Ag(CH2SiMe3)4(μ-dppm) 2]SO3CF3 complexes; the cation of the latter consists of a novel Au4Ag core with four AgI-AuI non-supported bonds.
