205304-59-2Relevant academic research and scientific papers
Ruthenium(II) hydrido complexes of S-methyldithiocarbazates
Maurya,Unny,Alekar,Gopinathan,Gopinathan
, p. 1058 - 1062 (2007/10/03)
Reactions of [RuHCl(CO)(PPh3)3] and [RuH2(CO)(PPh3)3] with schiff bases (HL) derived from S-methyldithiocarbazate and pyridine-2-aldehyde, 2-acetylpyridine, thiophene-2-aldehyde, 2- acetylthiophene and furan-2-aldehyde lead to the formation of neutral complexes of the type [RuX(CO)(PPh3)2L] (X = H or Cl). The probable stereochemistries of the complexes have been established on the basis of elemental analysis, IR, 1H and 13C NMR studies. The triphenylphosphines are trans leaving CO and H or Cl cis to each other in the complexes.
