205433-11-0Relevant articles and documents
η(3)-Allyl-cobalt(II) complexes
Grossheimann, G.,Jolly, P. W.
, p. 60 - 67 (2008/10/08)
(η(3)-Cyclooctenyl)Co(bisphosphine) compounds react with HBF4 in thepresence of alkenes with oxidation of the metal to give the novel, para magnetic organocobalt(II) species [(η(3)-cyclooctenyl)Co(bisphosphine)](+)BF4(-). (η(3)-2-RC3H4)Co(bisphosphine) complexes react similarly. The Co(II) compounds form adducts with CO and NO (the latter being diamagnetic) and undergo facile chemical and electrochemical reduction.