20552-76-5Relevant articles and documents
Transformation of acid chlorides into aldehydes by reduction of in-situ formed acyltributylphosphonium ions with zinc-copper couple or zinc
Maeda, Hatsuo,Maki, Toshihide,Ohmori, Hidenobu
, p. 2247 - 2250 (2007/10/02)
Transformation of acid chlorides into the corresponding aldehydes without over-reduction to alcohols was effectively achieved by the reduction of acyltributylphosphonium ions, formed in-situ from the chlorides and tributylphosphine in CH3CN, with Zn-Cu couple or Zn in the presence of CH3SO3H under an N2 atmosphere.