205657-13-2Relevant articles and documents
Rhodium (III) ditertiary stibine complexes
Hill, Angela M.,Levason, William,Webster, Michael
, p. 203 - 206 (2008/10/08)
The rhodium (III) distibine complexes trans-[Rh(L-L)2X2]Y (L-L=Ph2Sb(CH2) 3SbPh2 or o-C6H4(SbMe2)2; X=Cl, Br or I; Y=X or BF4) have been prepared and studied by UV-Vis, 1H and 103Rh NMR spectroscopies and electrospray mass spectrometry. The 103Rh NMR spectroscopic data are reported and compared with data on related phosphine and arsine complexes. The single crystal X-ray structure of trans-[Rh{Ph2Sb(CH2)3SbPh2} 2Cl2] [ClO4] is reported (Rh-Sb=2.594(2), 2.611(2); Rh-Cl=2.369(7) ?).