20568-04-1Relevant academic research and scientific papers
Pd/C-Catalyzed Hydrogenation of Substituted 5-Acyl-1,3-dioxanes
Borisova, Yu. G.,Daminev, R. R.,Musin, A. I.,Raskildina, G. Z.,Yakupov, N. V.,Zlotskii, S. S.
, p. 1619 - 1622 (2021/11/01)
Abstract: Hydrogenation of substituted 5-acyl-1,3-dioxanes in the presence of a Pd/C catalyst leads to the formation of substituted 1,3-dioxane alcohols as the only reaction products. The effect of a number of factors (temperature, rate of hydrogen and substrate supply) on the conversion of the ketone and the selectivity of the formation of alcohol was investigated.
SYNTHESIS OF 5-ALKENYL-1,3-DIOXANES
Lesnikova, E. T.,Zlotskii, S. S.,Rakhmankulov, D. L.
, p. 30 - 32 (2007/10/02)
Cyclic acetals containing alkenyl groups were obtained from 5-methyl-5-acetyl-1,3-dioxane.The 1,3-dioxane fragment does not interfere in reduction of the carbonyl group, nor in participation of the carbonyl group in Wittig and Grignard reactions.
