205681-08-9

Upstream product

• 35692-59-2 (1S,2S,4S,6R)-1-methyl-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]heptan-2-ol 
• 205681-04-5 (1S,2S,3R,5R)-3-benzyloxy-1,5-bis(tert-butyldimethylsilyloxy)-2-(hydroxymethyl)cyclohexane 
• 205681-03-4 (1S,3R,5R)-3-benzyloxy-1,5-bis(tert-butyldimethylsilyloxy)-2-methylenecyclohexane 
• 205681-06-7 (1S,2R,3R,5S)-3-benzyloxy-5-(tert-butyldimethylsilyloxy)-2-hydroxymethyl-cyclohexanol 
• 132870-50-9 (1S,2S,4R,6R)-2-(tert-butyldimethylsilyloxy)-4-acetyloxy-1-methyl-7-oxabicyclo[4.1.0]heptane 
• 205681-01-2 (1S,2S,4R,6R)-2-(tert-butyldimethylsilyloxy)-4-acetyl-1-methyl-7-oxabicyclo[4.1.0]heptane 
• 132870-51-0 (1R,3R,5S,6S)-5-(tert-butyldimethylsilyloxy)-6-methyl-7-oxabicyclo[4.1.0]heptan-3-ol 
• 121289-21-2 (1R,3S,5R)-3,5-bis(tert-butyldimethylsilyloxy)-2-methylenecyclohexanol 
• 121289-20-1 (1S,2S,4R,6R)-2,4-bis(tert-butyldimethylsilyloxy)-1-methyl-7-oxabicyclo[4.1.0]heptane 
• 121289-19-8 tert-butyl-[(1S,2S,4R,6R)-4-iso-propenyl-1-methyl-7-oxabicyclo[4.1.0]hept-2-yloxy]dimethylsilane 
• 6485-40-1 (R)-Carvone 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 36616-60-1 (1R,4R,6R)-4-isopropenyl-1-methyl-7-oxabicyclo[4.1.0]heptan-2-one 
• 205681-07-8 (2R,5R,7R,9S,10S)-5-benzyloxy-7-(tert-butyldimethylsilyloxy)-2-phenylhexahydrobenzo[1.3]dioxine 

Downstream Products

• 205681-14-7 (2R,5R,7R,9S,10S)-7-guanin-9-yl-5-benzyloxy-2-phenylhexahydrobenzo[1.3]dioxine 
• 205681-11-4 (2R,5R,7R,9S,10S)-7-adenin-9-yl-5-benzyloxy-2-phenylhexahydrobenzo[1.3]dioxine 
• 205681-15-8 (1S,2R,3R,5S)-5-guanin-9-yl-3-benzyloxy-2-(hydroxymethyl)cyclohexanol 
• 205681-12-5 (1S,2R,3R,5S)-5-adenin-9-yl-3-benzyloxy-2-(hydroxymethyl)cyclohexanol 
• 205681-10-3 (2R,5R,7S,9S,10S)-5-benzyloxy-2-phenylhexahydrobenzo[1.3]dioxin-7-ol 

Relevant academic research and scientific papers

Enantioselective approach to the synthesis of cyclohexane carbocyclic nucleosides

(R)-(-)-Carvone was used as starting material for the synthesis of a new series of 2-(hydroxymethyl)-cyclohexane-1,3-diol nucleosides. The enantioselective precursors of the nucleoside analogues were obtained via a stereo- and regioselective hydroboration reaction. The compounds have equatorial oriented base moieties despite the presence of three other axial substituents.