205877-03-8Relevant academic research and scientific papers
Reactions of group 4 metal cyclopentadienyl trifluorides with a trimeric iminoalane
Wessel, Helge,Rennekamp, Carsten,Roesky, Herbert W.,Montero, Mavis L.,Müller, Peter,Usón, Lsabel
, p. 1919 - 1921 (2008/10/08)
Reaction of CpMF3 (M = Ti, Zr) with [MeAlN(2,6-iPr2C6H3)]3 leads to fluorine-nitrogen exchange and the formation of isostructural adamantanelike cages. This reaction proceeds with activation of metal-fluorine bonds and can be regarded as a new route to aluminum-containing mixed group 4 amidofluorides.
