206051-34-5

Basic information

• Product Name: (C₅H₅)2Zr(2,4,6-OC₆H₂Me₃)2
• CAS NO: 206051-34-5
• Molecular Weight: 491.785
• Mol File: 206051-34-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₅H₅)2Zr(2,4,6-OC₆H₂Me₃)2(CAS DataBase Reference)
• NIST Chemistry Reference: (C₅H₅)2Zr(2,4,6-OC₆H₂Me₃)2(206051-34-5)
• EPA Substance Registry System: (C₅H₅)2Zr(2,4,6-OC₆H₂Me₃)2(206051-34-5)

Safety Data

• Hazardous Substances Data: 206051-34-5(Hazardous Substances Data)

Upstream product

• 12636-72-5 bis(cyclopentadienyl)dimethylzirconium(IV) 
• 527-60-6 Mesitol 

Relevant articles and documents

New O- and N-bonded zirconocene complexes and their catalytic properties in ethylene polymerization. X-ray crystal structure of (C5H5)2Zr{2,6-OC6H 3(CH3)2}2, (C5H5)2Zr{2,4,6-OC6H 2(CH3)3}2

A series of zirconocene complexes of formula Cp2ZrMe2-nLn where Cp = C5H-5, Me = methyl, L = pyrazolyl, bis(N,N′-phenylformamidinato), or substituted aryloxide and n = 1,2, were synthesized by reaction of Cp2ZrCl2 and Cp2ZrMe2 with LiL or HL, respectively. The structures of Cp2Zr(2,6-OC6H3Me2)2, Cp2Zr(2,4,6-OC6H2Me3)2 and Cp2ZrMe{CH(NC6H5)2} were determined by single crystal X-ray diffraction. The complexes demonstrate appreciable activity for ethylene polymerization when used as cocatalysts with methylaluminoxane and dimethylanilinium tetrafluorophenylborate.