20614-48-6

Basic information

• Product Name: 1-(benzylsulfanyl)but-3-en-2-ol
• Synonyms: 1-(benzylsulfanyl)but-3-en-2-ol
• CAS NO: 20614-48-6
• Molecular Weight: 194.298
• Mol File: 20614-48-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(benzylsulfanyl)but-3-en-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(benzylsulfanyl)but-3-en-2-ol(20614-48-6)
• EPA Substance Registry System: 1-(benzylsulfanyl)but-3-en-2-ol(20614-48-6)

Safety Data

• Hazardous Substances Data: 20614-48-6(Hazardous Substances Data)

Upstream product

• 6304-94-5 benzylmercaptoacetaldehyde dimethyl acetal 
• 7401-37-8 benzylsulfanylacetaldehyde 
• 1826-67-1 vinyl magnesium bromide 
• 100-53-8 phenylmethanethiol 
• 930-22-3 epoxybutene 

Relevant articles and documents

Comparison of the reaction of benzylammonium N-methylides with that of benzylsulfonium S-methylides

Allylbenzylsulfonium S-methylides 8S and dibenzylsulfonium S-methylides 18S have been generated by the fluoride ion-induced desilylation of S- benzyl-S-[(trimethylsilyl)methyl](alk-2-enyl)sulfonium salts 4S and S- benzyl-S-[(trimethylsilyl)methyl](4-substituted benzyl)sulfonium salts 7S, and the isomerized products are compared with those of the corresponding N- methylides. S-Methylides 8S selectively rearrange toward the allyl groups (path a in Chart 2), whereas rearrangement to the benzyl groups (path b) competitively occurs in N-methylides 8N. Isomerization of S-methylides 18S to S-benzylides 19S and 20S competes with sigmatropic rearrangement to the benzyl groups (paths a and b in Chart 3), whereas the isomerization of N- methylides 18N is not observed.