20643-23-6Relevant academic research and scientific papers
Reaction of Substituted Hydrazones with Thionyl Chloride and Sulfuryl Chloride
Meier, Herbert,Trickes, Georg,Laping, Elisabeth,Merkle, Ursula
, p. 183 - 192 (2007/10/02)
Treatment of acetylhydrazones 2, ethoxycarbonylhydrazones 3, p-tolylsulfonylhydrazones 4 or semicarbazones 5 with thionyl chloride leads to the 1,2,3-thiadiazoles 6a-o.Sulfuryl chloride on the other hand accomplishes the transfer of chlorine without incorporating a sulfur atom.The new synthesized 1,2,3-thiadiazoles 6g-o are characterized in detail by spectroscopic methods.
