206437-62-9

Basic information

• Product Name: (η(5)-cyclopentadienyltitanio)benzenesulfonamide
• Synonyms: (η(5)-cyclopentadienyltitanio)benzenesulfonamide
• CAS NO: 206437-62-9
• Molecular Weight: 269.16
• Mol File: 206437-62-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (η(5)-cyclopentadienyltitanio)benzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: (η(5)-cyclopentadienyltitanio)benzenesulfonamide(206437-62-9)
• EPA Substance Registry System: (η(5)-cyclopentadienyltitanio)benzenesulfonamide(206437-62-9)

Safety Data

• Hazardous Substances Data: 206437-62-9(Hazardous Substances Data)

Upstream product

• 1271-19-8 bis(cyclopentadienyl)titanium dichloride 

Relevant articles and documents

Synthesis of Benzenesulfonyl Derivatives with N-Metal Bonds

Reaction of p-NH2C6H4SO2NH2 with (Bu3Sn)2O was used to prepare p-Bu3SnNHC6H4SO2NHSnBu3, whose transmetalation with (η5-C5H5)2V(Cp2V) gave p-CpVNHC6H4SO2NHVCp. When exposed to air, the latter rapidly converted to p-O=VNHC6H4SO2NHVCp and then to the parent sulfonamide. Sulfonamides PhSO2NHMCp were synthesized in a similar way from PhSO2NHSnBu3 and Cp2M or Cp2MCl2 (M = V, Ti, Nb, Mo).