206438-96-2Relevant academic research and scientific papers
Stereoselective hetero-claisen rearrangement of camphor derived oxazoline-N-oxides
Dalko, Peter I.,Langlois, Yves
, p. 2107 - 2110 (2007/10/03)
Camphor derived oxazoline-N-oxides in the presence of various acylating agents afforded α-acyloxyoxazolines resulting from a diastereoselective [3,3] rearrangement. The configuration of the newly formed asymmetric center was established by chemical correlation. The observed diastereoselectivity accounts a concerted rather than a stepwise process.
