206449-75-4Relevant articles and documents
A facile aldol-isomerization route to 3-alkyldihydropyridinone with a chiral azocine ring
Torisawa, Yasuhiro,Soe, Than,Katoh, Chiaki,Motohashi, Yumiko,Nishida, Atsushi,Hino, Tohru,Nakagawa, Masako
, p. 655 - 659 (2007/10/03)
An efficient protocol was devised for the synthesis of the chiral dihydropyridinone derivative (19), which involves an aldol-type coupling reaction between N-alkylpiperidin-2-one and Garner aldehyde followed by a silane-Rh-mediated olefin isomerization.