20676-80-6Relevant academic research and scientific papers
Pd-Catalyzed P–C Cross-Coupling of Aryl Bromides and Triflates with Hydroxymethylphosphine Sulfide Derivatives
Ohta, Hidetoshi,Xue, Qian,Hayashi, Minoru
supporting information, p. 735 - 738 (2018/02/21)
The development of a versatile process for phosphine synthesis has attracted considerable interest because organophosphines are indispensable for organic synthesis. Previously, we developed a Pd-catalyzed P–C coupling reaction for hydroxymethylphosphine s
Pd-catalyzed P-C cross-coupling reactions for versatile triarylphosphine synthesis
Hayashi, Minoru,Matsuura, Takashi,Tanaka, Ippei,Ohta, Hidetoshi,Watanabe, Yutaka
supporting information, p. 628 - 631 (2013/04/11)
Practical and versatile syntheses of tertiary phosphine derivatives have been achieved by palladium-catalyzed deformylative P-C cross-coupling reactions of hydroxymethylphosphine derivatives. Sequential couplings of orthogonally protected precursors provide a simple and practical route toward a variety of tertiary phosphine derivatives having aryl substituents in any combination.
Radical phosphination of organic halides and alkyl imidazole-1- carbothioates
Sato, Akinori,Yorimitsu, Hideki,Oshima, Koichiro
, p. 4240 - 4241 (2007/10/03)
Taking advantage of a radical-based methodology, mild and chemoselective phosphination reactions of organic halide and alkyl imidazole-1-carbothioates have been developed. The mild reaction conditions allow labile functional groups to survive during the reaction. Copyright
THE ORTHO-LITHIATION OF PHENYL GROUPS AND α-LITHATION OF ALKYL GROUPS OF THIOPHOSPHORYL COMPOUNDS
Yoshifuji, Masaaki,Ishizuka, Tadao,Choi, Yoon Jung,Inamoto, Naoki
, p. 553 - 556 (2007/10/02)
Diphenylphosphintothioyl compounds were ortho-lithated and alkyldiphenyl phosphine sulfides were α-lithiated and the resulting lithio compounds reacted to give the corresponding o- and α-substitued products.
