20677-03-6Relevant academic research and scientific papers
Microwave assisted P–C coupling reactions without directly added P-ligands
Henyecz, Réka,Huszár, Bianka,Keglevich, Gy?rgy,Mucsi, Zoltán
, (2021/12/24)
Our group introduced a green protocol for the Pd(OAc)2- or NiCl2-catalyzed P–C coupling reaction of aryl halides and various > P(O)H-compounds under MW conditions without directly added P-ligands. The reactivity of a few aryl derivatives in the Pd(OAc)2-catalyzed Hirao reaction was also studied. An induction period was observed in the reaction of bromobenzene and diphenylphosphine oxide. Finally, the less known copper(I)-promoted P–C coupling reactions were investigated experimentally. The mechanism was explored by quantum chemical calculations.
Hypervalent iodine in synthesis. 52. Palladium-catalyzed arylation of O,O-dialkyl phosphites with diaryliodonium salts: A convenient method for synthesis of arylphosphonates
Zhou,Chen
, p. 3289 - 3294 (2007/10/03)
Palladium-catalyzed coupling reaction of diaryliodonium salts with O,O-dialkyl phosphites gave arylphosphonates in good yields.
Synthesis of arylphosphonates by arylation of phosphite anions using diaryliodonium salts
Liu,Chen
, p. 373 - 374 (2007/10/02)
An efficient synthesis of arylphosphonates 3 is described. The method involves simple stirring of the dialkyl phosphite salts 2 with diaryliodonium salts 1 in dimethylformamide.
