20710-50-3Relevant academic research and scientific papers
A Convenient Preparation of Bis(thioacyl) Sulfides
Kato, Shinzi,Masumoto, Hiroki,Kimura, Masahiro,Murai, Toshiaki,Ishida, Masaru
, p. 304 - 306 (2007/10/02)
Bis(thioacyl) sulfides are prepared in 60-90percent yield in a one-pot reaction of piperidinium or alkali metal dithiocarboxylates with 2-chloro-1-methylpyridinium iodide at room temperature.
Preparation and Some Reactions of Thioacyl Diphenylthiophosphinoyl and Thioacyl Diphenylphosphino Sulfides
Kato, Shinzi,Goto, Masahisa,Hattori, Rikizoh,Nishiwaki, Koh-ichi,Mizuta, Masateru,Ishida, Masaru
, p. 1668 - 1683 (2007/10/02)
The reaction of sodium or caesium dithiocarboxylates with diphenylthiophosphinic and diphenylselenophosphinic chlorides gives purple thioacyl diphenylthiophosphinoyl 5 and dark green thioacyl diphenylselenophosphinoyl sulfides 6, which are useful thioacylating reagents under mild reaction conditions.Thioacyl diphenylphosphino sulfides 22, which can be obtained by the similar method using diphenylphosphinous chlorides, react with methanol to yield the corresponding methyl dithiocarboxylates 15, while the reactions of 22 with N-chlorosuccinimide lead to hitherto unknown N-(thioacetylthio)succinimides 28.
