207290-22-0Relevant academic research and scientific papers
Relative M-X bond dissociation energies in 16-, 17- And 18-electron organotransition-metal complexes (X = halide, H)
Tilset, Mats,Hamon, Jean-Rene,Hamon, Paul
, p. 765 - 766 (1998)
The Fe-halide bonds in Cp*Fe(dppe)X (X = F, Cl, Br, I) complexes are weakened as a consequence of one and two-electron oxidations; the bond weakening decreases in the order F ? Cl a pronounced effect of apparent fluoride-to-metal backbonding as a consequence of the removal of electrons.
Preparation and Characterization of the Triflate Complex [Cp*(dppe)FeOSO2CF3]: A Convenient Access to Labile Five- and Six-Coordinate Iron(I) and Iron(II) Complexes
Hamon, Paul,Toupet, Loic,Roisnel, Thierry,Hamon, Jean-René,Lapinte, Claude
, p. 84 - 93 (2019/12/12)
Treatment of the iron hydride [Cp*(dppe)FeH] (1) with methyl triflate (CH3OSO2CF3) yielded the iron triflate adduct [Cp*(dppe)FeOSO2CF3] (4, 85 %). In the solid state, the triflate is coordinated at t
Theoretical, thermodynamic, spectroscopic, and structural studies of the consequences of one-electron oxidation on the Fe-X bonds in 17- and 18-electron Cp*Fe(dppe)X complexes (X=F, C1, Br, I, H, CH3)
Tilset,Fjeldahl,Hamon,Hamon,Toupet,Saillard,Costuas,Haynes
, p. 9984 - 10000 (2007/10/03)
The compounds Cp*Fe(dppe)X ([Fe*]X)and the corresponding cation radicals [Fe*]X+ are available for the series X=F, C1, Br, I, H, CH3. This has allowed for a detailed investigation of the dependence of the nature of Fe-X bonding on th
