207293-02-5Relevant academic research and scientific papers
Convenient synthesis of α- and β-2-deoxyglycosides
Castro-Palomino, Julio C.,Schmidt, Richard R.
, p. 501 - 503 (2007/10/03)
Readily available O-(2-O-thiobenzoyl-mannopyranosyl)trichloroacetimidate 4a gave with glucosides 7 and 8 as glycosyl acceptors exclusively α-linked disaccharides 9α and 10α. Accordingly, from O-(2-O-thiobenzoyl-glucopyranosyl)trichloroacetimidate 4b exclusively β-linked disaccharides 9β and 10β were obtained. Radical initiated deoxygenation with Bu3SnH/AIBN directly furnished 2-deoxyglycosides 11α,β and 12α,β.
