2073-32-7Relevant articles and documents
Direct and Catalytic Amide Synthesis from Ketones via Transoximation and Beckmann Rearrangement under Mild Conditions
Hyodo, Kengo,Hasegawa, Genna,Oishi, Naoki,Kuroda, Kazuma,Uchida, Kingo
, p. 13080 - 13087 (2018/11/02)
The Br?nsted acid-catalyzed synthesis of secondary amides from ketones under mild conditions is described via transoximation and Beckmann rearrangement using O-protected oximes as more stable equivalents of explosive O-protected hydroxylamines. This methodology could be applied to highly rearrangement-selective amide synthesis from α-branched alkyl aryl ketones and performed on a 1-g scale. The presence of water is essential for this reaction, and its role was clarified by isotope-labeling experiments.
Amidino derivatives useful as nitric oxide synthase inhibitors
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, (2008/06/13)
The current invention discloses useful pharmaceutical compositions containing amidino derivative useful as nitric oxide synthase inhibitors.
Novel Approach to Lactams via (Triisopropylsilyl)azidohydrin Formation and Photoinduced Schmidt Rearrangement
Evans, P. Andrew,Modi, Dilip P.
, p. 6662 - 6663 (2007/10/03)
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