207388-18-9Relevant academic research and scientific papers
Selective C-Cl versus P-Cl activation - Syntheses of complexes with P-Cl functional phosphinomethyl bridges η2,μ2-{P(R)Cl-CH2}
MacHnitzki, Peter,Stelzer, Othmar,Sheldrick, William S.,Landgrafe, Claudia
, p. 207 - 210 (1998)
On reaction of chloromethylchlorophosphines Cl(R)P-CH2-Cl with Pd(Ph3P)4 the C-Cl bond is selectively activated by oxidative addition to Pd(0), unusual dipalladium complexes with P-Cl functional η2,μ2-{CH2-P(R)Cl} bridges being formed with high diastereoselectivity. The X-ray structure of 3a (R=tBu) reveals a chair-shaped Pd2P2C2 six-membered ring system with the substituents (Cl, tBu) at the two m2-P atoms in cis-position.
