207400-19-9

Upstream product

• 207400-13-3 (2,4-di-tert-butyl-6-(N,N-dimethylaminomethyl)phenyl)Ge(2,4,6-iPr₃C₆H₂) 
• 74-88-4 methyl iodide 
• 207400-09-7 (2,4-di-tert-butyl-6-((dimethylamino)methyl)phenyl)germanium chloride 
• 74226-59-8 2,4,6-triisopropylphenyl lithium 

Relevant academic research and scientific papers

Germylenes and germyl cations with the 2,4-Di-tert-butyl-6-(N,N-dimethylaminomethyl)phenyl ligand

The 2,4-di-tert-butyl-6-(N,N-dimethylaminomethyl)phenyl (Mamx) ligand allows the synthesis of the germylenes MamxGeCl (1), Mamx2Ge (2), Mamx-(Tip)Ge (3; Tip = 2,4,6-iPr3C6H2), MamxGeN3 (4), MamxGeN(SiMe3)2 (5), and MamxGe[Fe(CO)2Cp*] (6), which are all stabilized by coordination of the amino side chain. Reactions of 2 and 3 with MeI yield the ionic compounds Mamx(Tip)(Me)Ge+I- (7) and Mamx2(Me)-Ge+I- (8), respectively; the X-ray crystal structure of 7 shows a trigonal-planar coordination at the Ge center and a nearly perpendicular Ge-N bond.