207409-22-1Relevant academic research and scientific papers
Stereoselective synthesis of (E)-β-tributylstannyl-α,β-unsaturated ketones: Construction of a key intermediate for the total synthesis of zoanthamine
Nielsen, Thomas E.,Tanner, David
, p. 6366 - 6371 (2007/10/03)
(E)-β-Trialkylstannyl-α,β-unsaturated ketones are readily available from secondary propargylic alcohols via a two-step sequence involving highly regio- and stereoselective Pd(0)-catalyzed hydrostannation followed by mild oxidation (TPAP). The methodology
