20744-06-3

Upstream product

• 126861-80-1 (4-Methoxy-phenoxy)-acetic acid 2-thioxo-2H-pyridin-1-yl ester 
• 107-13-1 acrylonitrile 
• 150-76-5 4-methoxy-phenol 
• 6267-37-4 1-(3-bromopropoxy)-4-methoxybenzene 
• 151-50-8 potassium cyanide 

Downstream Products

• 858202-32-1 6-(4-methoxy-phenoxy)-1-[3-(4-methoxy-phenoxy)-propyl]-4-methyl-hexylamine 
• 858202-36-5 6-(4-methoxy-phenoxy)-1-[3-(4-methoxy-phenoxy)-propyl]-hexylamine 
• 859987-98-7 1,9-bis-(4-methoxy-phenoxy)-7-methyl-nonan-4-one 
• 859988-04-8 1,9-bis-(4-methoxy-phenoxy)-nonan-4-one 

Relevant academic research and scientific papers

Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis

Hydroalkoxymethylation of electron-deficient alkenes using alkoxymethyltrifluoroborates by photoredox catalysis has been developed. Highly reactive alkoxymethyl radicals can be easily generated from oxidation of alkoxymethyltrifluoroborates via a visible-light-induced SET process.

BIOMIMETIC RADICAL CYCLISATIONS: SYNTHESIS AND BIOSYNTHESIS OF BENZODIHYDRO-PYRANES AND -FURANS

Aryloxymethylene radicals generated by decarboxilation of the thiohydroxamate esters derived from acids (8a), (10a), and (12) undergo 6-endo cyclisation yielding (9), (11), and (14) respectively, mimicking the unusual biosynthetic reactions involved in formation of (1), (3), and (4) in nature.