207446-55-7Relevant academic research and scientific papers
Influence of the trans substituent on N2 bonding in iron(II) - Phosphane complexes: Structure, synthesis, and properties of the monomeric adducts trans-[FeXN2(depe)2]BPh4, X = Cl, Br
Wiesler, Beatrix E.,Lehnert, Nicolai,Tuczek, Felix,Neuhausen, Joerg,Tremel, Wolfgang
, p. 815 - 817 (1998)
Not a dimer but a monomer was found in the X-ray structure analysis of the complex 'trans-[{FeCl-(depe)2}2(μ-N2)](BPh4)2' (depe = Et2PCH2CH2- PEt2). The complexes [FeXN2(depe)2]BPh4 (X = Cl, Br; structure of the cation for X = Cl shown on the right) are much less stable than the analogous hydride compounds and undergo N2 exchange at room temperature even in the solid state.
