207463-06-7Relevant academic research and scientific papers
3-ferrocenyl-3-(1-naphthyl)cyclopropene. Synthesis, structure, and chemical transformations
Klimova,Ruiz Ramirez,Klimova Berestneva,Martinez Garcia,Moreno-Esparza,Alvarez Toledano,Toscano
, p. 482 - 489 (1998)
Crystalline 3-ferrocenyl-3-(1-naphthyl)cyclopropene was prepared by dehydrobromination of Z- and E-2-bromo-1-ferrocenyl-1-(1-naphthyl)-cyclopropanes by ButOK in DMSO. The resulting compound and the starting Z-monobromocyclopropane were characterized by X-ray diffraction analysis. The obtained cyclopropene reacts with 1,3-diphenylisobenzofuran to give a [4+2|-cycloadduct. The small ring opens upon treatment with HBF4 etherate to afford isomeric Z- and E-prop-1-enes and 1-ferrocenyl-3H-benzo[e]indene. Thermolysis of this cyclopropene results in the formation of 1-ferrocenyl-9bH-benzo[e]indene. In all cases, opening of the small ring is accompanied by exclusive alkylation of the naphthalene moiety.
