207618-37-9Relevant academic research and scientific papers
The azide-nitrilimine analogy in aluminum chemistry
Emig, Norbert,Gabbai, Francois P.,Krautscheid, Harald,Reau, Regis,Bertrand, Guy
, p. 989 - 992 (1998)
Tetracoordinate aluminum derivatives featuring an AINNCR fragment are stable and possess a rich structural diversity, as exemplified by the nitrilimines 1 and 2, similar to that observed for the related azides. Compound 1 is the first structurally characterized six-membered AIN heterocycle in which the nitrogen and aluminum centers exhibit different coordination numbers. R=P(NiPr2)2; R'=iBu; E=N, CR.
