207690-34-4Relevant academic research and scientific papers
Dinuclear platinum(II) complex bridged by an acetylacetonate(3-) anion
Okeya, Seichi,Kusuyama, Yoshiaki,Isobe, Kiyoshi,Nakamura, Yukio,Kawaguchi, Shinichi
, p. 117 - 123 (1998)
[Pt(acac)2] reacted with twice the molar amount of PPh3 in hot MeOH to afford the first metal complex with an acetylacetonate trianion, [Pt2(μ-acac(3-))(PPh3)4](acac), as a major product via [Pt(acac)(PPh3)2](acac). The η3:C, O-bridging structure of the trianion was deduced by 1H, 13C, 31P and 195Pt NMR spectra. This reaction system also afforded a minor product of an acetylacetonate dianion complex, [Pt(η3-acac(2-))(PPh3)2]; while [Pd(acac)2] gave only [Pd(η3-acac(2-))(PPh3)2] in the same reaction conditions.
