20772-64-9

Upstream product

• 106-49-0 p-toluidine 
• 148-53-8 3-methoxy-2-hydroxybenzaldehyde 

Downstream Products

• 303089-91-0 RuCl₂(PPh₃)2(2-O-3-OMe-C₆H₃CHNC₆H₄Me-4) 
• 303089-92-1 RuCl₂(AsPh₃)2(2-O-3-OMe-C₆H₃CHNC₆H₄Me-4) 
• 303089-94-3 RuBr₂(PPh₃)2(2-O-3-OMe-C₆H₃CHNC₆H₄Me-4) 
• 303089-93-2 RuBr₂(AsPh₃)2(2-O-3-OMe-C₆H₃CHNC₆H₄Me-4) 

Relevant academic research and scientific papers

Synthesis, crystal structure, and kinetics of the thermal decomposition of the nickel(II) complex of the Schiff base 2-[(4-methylphenylimino)methyl]-6- methoxyphenol

A new dinuclear complex, [Ni2(H2O)L 4]·5H2O, consisting of chelating bidentate and bridging tridentate coordinated 2-[(4-methylphenylimino)methyl]-6-methoxyphenol (HL) Schiff base ligands and water molecules has

Catalytic investigation of Pd(II) complexes over Heck–Mizoroki reaction: Tailored synthesis, characterization and density functional theory

Tailored reaction of Schiff base ligands with palladium(II) chloride and imidazole afford three complexes of formula [Pd(II)(L)(imdz)2]Cl, which are L = 2-((E)-(p-lylimino)methyl)-6-methoxyphenol (complex 1), 2-methoxy-6-((E)-(phenylimine)methyl)phenol (complex 2) and 2-((E)-(4-chlorophenyl-imino)methyl)-6-methoxyphenol (complex 3). Compounds were characterized with elemental analysis, molar conductance, electronic spectroscopy, ESI-MS, FT-IR, TGA, 1H-NMR and 13C-NMR. Molecular structure and different quantum chemical parameters were calculated using the B3LYP basis set of density functional theory with the standard 6-311+G (d, 2p) level. The catalytic potential of 1-3 was examined over Heck-Mizoroki reaction and found in order of 1 > 2 > 3.

Synthesis, physicochemical characteristics and biological activity of ruthenium(III) complexes with bidentate (N, O) Schiff bases

The octahedral ruthenium(III) complexes have been prepared with bidentate Schiff bases derived from condensation of 2-amino-4-methylpyridine and 4-methylaniline with aromatic aldehydes. The obtained complexes were characterized on the basis of their eleme

Synthesis, characterization, crystal structure and antibacterial activities of transition metal(II) complexes of schiff base

Five complexes of the general composition [ML2(NO 3)2] (1-5) [M = Mn(II),Co(II), Ni(II), Cu(II), Cd(II)] were synthesized from the reaction of a Schiff base ligand 2-[(4- methylphenylimino)methyl]-6-methoxy-phenol (C1

Synthesis, characterization and thermal studies of Rh(III) complexes derived from bidentate schiff bases

The Schiff base ligands were derived from 2-hydroxy-3-methoxybenzaldehyde (HL1), 4-hydroxy-3-methoxybenzaldehyde (HL2), with p-toluidine and 3-hydroxybenzaldehyde with 4-hydroxybenzhydrazide (HL 3) and 3-hydroxy-2-naphthoi

Synthesis and characterization of the transition metal complexes: Their alcohol oxidation and electrochemical properties

Five Schiff base ligands, HA1, HA2, H 2L1-H2L3, and their Co(II), Mn(III) and Ru(III) complexes, have been synthesized and characterized by analytical, spectroscopic, conductance, magnetic

Mechanically induced reactions in organic solids: Liquid eutectics or solid-state processes?

The solvent-free reaction between o-vanillin and p-toluidine was investigated using NMR, DSC and XRD analyses. At room temperature, o-vanillin and p-toluidine react in a liquid eutectic formed upon grinding, while below 10 °C the same materials appear to react without the formation of a liquid phase, which most likely remains hidden behind solid reactants and reaction products.

Synthesis, spectroscopic and structural characterization of trivalent chromium, manganese, iron and cobalt complexes with schiff bases derived from o-vanillin

A series of new coordination complexes involving chromium(III), manganese(III), iron(III) and cobalt(III) with Schiff bases derived from condensation of o-vanillin with diamines viz. 1,2-diaminoethane, 1,3-diaminopropane, 1,4-diaminobutane or 1,2-diaminob

Synthesis, crystal structure and spectroscopic study of para substituted 2-hydroxy-3-methoxybenzalideneanilines

Eight Schiff bases derived from 2-hydroxy-3-methoxybenzaldehyde and different para substituted anilines have been synthesized and their structures were elucidated by physical measurements and FT-IR. NMR assignments were made using 1H, 13/

Understanding solid/solid organic reactions

The concept of an organic reaction between two macroscopic solid particles is investigated. Thus, we study several reactions that have been recently reported to proceed "in the solid phase" and clearly show that, in most cases, grinding the two solid reactants together results in the formation of a liquid phase. This is true both for catalytic transformations (e.g., aldol condensations and oligomerization of benzylic compounds) and for noncatalytic reactions (Baeyer - Villiger oxidations, oxidative coupling of naphthols using iron chloride, condensation of amines and aldehydes to form azomethines, homo-etherification of benzylic alcohols using p-toluenesulfonic acid, and nuclear aromatic bromination with NBS). This liquefaction implies the existence of a eutectic mixture with Tfusion below ambient temperature (although both reagents have higher than ambient melting points). In cases where heating is required, it is again clear that a phase change (from solid to liquid) occurs, explaining the observed reaction kinetics. On the basis of 19 experimental examples, we discuss the possibility of solid-phase organic reactions and the implications of these findings to the reaction between two solid reagents. A general description of such reactive systems is proposed, based on a consideration of the potential for eutectic (or peritectic) formation between the constituents of the liquid phases that arise during the process of mechanical mixing of the solid reagents and products.