20781-61-7Relevant academic research and scientific papers
Synthesis of aryl fluorides from potassium aryltrifluoroborates and selectfluor mediated by iron(III) chloride
Dubbaka, Srinivas Reddy,Gadde, Satyanarayana,Narreddula, Venkateswara Reddy
, p. 854 - 860 (2015)
The synthesis of fluorinated arenes by the iron-mediated fluorination of potassium aryltrifluoroborates with Selectfluor and potassium fluoride is described. The fluorination reaction uses commercially available reagents and without requiring the addition
Caesium Fluoroxysulphate as a Mild Fluorinating Agent for the Fluorination of Alkoxy-substituted Benzene and Naphthalene Derivatives
Stavber, Stojan,Zupan, Marko
, p. 148 (1981)
Room-temperature fluorination of alkoxy-substituted benzene derivatives with caesium fluoroxysulphate in the presence of boron trifluoride as catalyst resulted in the formation of ortho- and para-fluoro-substituted products, the ratio being dependent on the size of the alkoxy-group, while reactions with 2-alkoxynaphthalene derivatives resulted in the formation of 1,1-difluoro-2-oxo-1,2-dihydronaphthalene as well as 1-fluoro-substituted products.
Decarboxylative etherification of aromatic carboxylic acids
Bhadra, Sukalyan,Dzik, Wojciech I.,Goossen, Lukas J.
, p. 9938 - 9941 (2012/08/08)
Decarboxylative Chan-Evans-Lam-type couplings are presented as a new strategy for the regiospecific construction of diaryl and alkyl aryl ethers starting from easily available aromatic carboxylic acids. They allow converting various aromatic carboxylate salts into the corresponding aryl ethers by reaction with alkyl orthosilicates or aryl borates, under aerobic conditions in the presence of silver carbonate as the decarboxylation catalyst and copper acetate as the cross-coupling catalyst.
