208039-77-4

Upstream product

• 208039-61-6 allyl (R)-2,3:(R)-4,6-di-O-benzylidene-α-D-glucopyranoside 
• 208039-63-8 (R)-2,3:(R)-4,6-di-O-benzylidene-D-glucose 
• 208039-73-0 (R)-2,3:(R)-4,6-di-O-benzylidene-D-glucitol 
• 76-83-5 trityl chloride 
• 93382-48-0 allyl 4,6-O-benzylidene-α-D-glucopyranoside 
• 208039-75-2 (R)-2,3:(R)-4,6-di-O-benzylidene-1-O-trityl-D-glucitol 

Downstream Products

• 1053616-65-1 2-[(2R,4S,5R)-2-Phenyl-4-((2S,4R,5S)-2-phenyl-5-trityloxymethyl-[1,3]dioxolan-4-yl)-5-trimethylsilanyloxy-[1,3]dioxan-5-yl]-thiazole 

Relevant academic research and scientific papers

Aldehyde-Promoted Addition of 2-(Trimethylsilyl)thiazole to α,α'-Dialkoxy Ketones: A New Way to Branched-Chain Monosaccharides

The reaction of 2-(trimethylsilyl)thiazole (2-TST) with several ketones was tested in the presence or absence of aldehydes. The keto aldehyde 5 (Scheme 2) was prepared from 1 via the hydroxy aldehyde 4 in 3 steps. It reacted with 2-TST to give, after desi