2081-76-7Relevant academic research and scientific papers
Planar chiral dialkoxysilane: Introduction of inherent chirality and high reactivity in conventional achiral alkene
Tomooka, Katsuhiko,Miyasaka, Shouji,Motomura, Shougo,Igawa, Kazunobu
supporting information, p. 7598 - 7602 (2014/07/07)
A simple eight-membered dialkoxysilane (E)-1 prepared from 2-pentene-1,5-diol, showed remarkably stable planar chirality along with high reactivity toward epoxidation, Diels-Alder reaction, and cycloaddition reaction with azide. Enriching alkenes: A simple eight-membered dialkoxysilane, prepared from 2-pentene-1,5-diol, shows remarkably stable planar chirality along with quite a high reactivity in epoxidation reactions, Diels-Alder reactions, and in cycloaddition reactions with azide (see scheme).
