208176-65-2Relevant academic research and scientific papers
Synthesis, spectral and redox studies of arylazopyridine palladium(II) salicylates
Roy, Ramakrishna,Das, Debasis,Sinha, Chittaranjan
, p. 141 - 146 (2007/10/03)
Arylazopyridinepalladium(II) complexes of salicylic acids of the formula [Pa(aap)(O O)] (3-5), where aap = 2-(arylazo)-pyridines and O O = salicyclic acid (SA, a), 3-formylsalicylic acid (3FSA, b), 5-formylsalicylic acid (SFSA, c), sulfosalicylic acid (SFSA, d) and 4-methyisalicylic acid (4MSA, 3) have been synthesized and characterized by elemental analyses, IR, UV-vis, 1H NMR spectra. The complexes have been found to show ligand- to ligand charge transfer (LLCT) transition in the visible region. The cyclic voltamograms exhibit two successive one electron responses corresponding to N=N reduction.
