208182-14-3Relevant academic research and scientific papers
The photomediated reaction of alkynes with cycloalkanes
Doohan, Roisin A.,Hannan, John J.,Geraghty, Niall W.A.
, p. 942 - 952 (2007/10/03)
In the presence of a photomediator such as benzophenone, alkynes with electron-withdrawing groups react with cycloalkanes to give vinyl cycloalkanes. The reaction involves the regiospecific addition of a photochemically generated cycloalkyl radical to the β-carbon of the alkyne. The stereochemical outcome of the reaction depends on the nature of the photomediator and alkyne used. The Royal Society of Chemistry 2006.
