208343-83-3Relevant academic research and scientific papers
Nitrosocarbonyl Intermediates as "Super-Enophiles": a Mild Method for Carbon-Nitrogen Bond Formation
Quadrelli, P.,Mella, M.,Caramella, P.
, p. 3232 - 3236 (2007/10/03)
Nitrosocarbonyl intermediates, generated at r.t. by the mild oxidation of nitrile oxides, undergo clean ene reactions with tetramethyl- and trimethyl-ethylene and with cyclohexene.With less substituted ethylenes the ene pathway is still active but the oxidation step of the nitrile oxides competes with the cycloadditions to the olefins. - Keywords: Cycloadditions; Ene reactions; Nitrile oxides; Nitroso compounds
