20837-12-1

Basic information

• Product Name: 2-bromo-2'-methoxy-1,1'-Biphenyl
• Synonyms: 2-bromo-2'-methoxy-1,1'-Biphenyl;2-Bromo-2'-Methoxybiphenyl;2'-Bomo-2-methoxybiphenyl
• CAS NO: 20837-12-1
• Molecular Formula: C₁₃H₁₁BrO
• Molecular Weight: 263
• Mol File: 20837-12-1.mol
• Article Data: 7

Chemical Properties

• Melting Point: 58 °C
• Boiling Point: 303.1±17.0 °C(Predicted)
• Appearance: /
• Density: 1.350±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 2-bromo-2'-methoxy-1,1'-Biphenyl(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-2'-methoxy-1,1'-Biphenyl(20837-12-1)
• EPA Substance Registry System: 2-bromo-2'-methoxy-1,1'-Biphenyl(20837-12-1)

Safety Data

• Hazardous Substances Data: 20837-12-1(Hazardous Substances Data)

Upstream product

• 583-55-1 1-Bromo-2-iodobenzene 
• 5720-06-9 2-Methoxyphenylboronic acid 

Downstream Products

• 1614231-59-2 C₃₀H₄₂AuClNOP 
• 1614230-85-1 N-(2'-(dicyclohexylphosphino)biphenyl-6-methoxy-3-yl)piperidine 
• 1614231-58-1 C₃₈H₅₀AuClNOP 
• 1614230-84-0 N-(2'-(diadamantylphosphino)biphenyl-6-methoxy-3-yl)piperidine 
• 1601392-91-9 C₂₇H₂₃O₄P 
• 402822-67-7 2-(diphenylphosphinyl)-2'-methoxyl-1,1'-biphenyl 
• 402822-70-2 2′-(diphenylphosphino)biphenyl-2-ol 
• 1432486-67-3 (P,S_P)-9-phenyl-9,10-dihydro-9-phosphaphenanthrene 
• 1432486-64-0 (P,S_P)-9-phenyl-9,10-dihydro-9-phosphaphenanthrene P-borane 
• 1432486-59-3 (S_P)-(2′-methoxybiphenyl-2-yl)(methyl)(phenyl)phosphine P-borane 
• 1432486-51-5 methyl (R_P)-(2′-methoxybiphenyl-2-yl)(phenyl)phosphinite P-borane 
• 1426051-52-6 bis(2'-methoxybiphenyl-2-yl)silane 
• 1401340-68-8 (2’-bromobiphenyl-2-yloxy)(tert-butyl)diphenylsilane 
• 1332483-65-4 (2'-methoxybiphenyl-2-yl)phenylphosphine oxide 

Relevant articles and documents

On the Origin of the Non-Planarity in Biarylsilyloxonium Ions

The structure determination of a series of biphenylsilyloxonium cations through NMR and XRD studies, supported by DFT calculations was carried out, allowing to get insights into the origin of the oxygen pyramidalization in biphenyl and binaphthylsilyl oxoniums. Low barrier of inversion in the oxygenyl series points toward a key role of the biaryl axis in the inversion of configuration at the oxygen center.

Palladium-catalyzed R2(O)P directed C(sp2)-H acetoxylation

A novel and efficient Pd-catalyzed C-H acetoxylation is described. The approach uses R2(O)P as a directing group to synthesize various substituted 2′-phosphorylbiphenyl-2-OAc compounds. Notably, the reaction exhibits smooth operation under mild conditions and shows good functional group tolerance. Products are obtained with high selectivity and yields. This journal is the Partner Organisations 2014.

Rhodium-catalyzed asymmetric synthesis of silicon-stereogenic dibenzooxasilines via enantioselective transmetalation

A rhodium-catalyzed asymmetric synthesis of silicon-stereogenic dibenzooxasilines has been developed. High enantioselectivities have been achieved by employing (S,S)-Me-Duphos as the ligand through " enantioselective transmetalation".