208708-80-9Relevant academic research and scientific papers
Diastereo-differentiating coupling of phenoxy radical moiety controlled by 2,4-pentanediol tether. Preparation of optically active Pummerer's ketone analogs
Yamaguchi, Kohei,Sugimura, Takashi,Nishida, Futoshi,Tai, Akira
, p. 4521 - 4524 (2007/10/03)
The highly diastereo-differentiating coupling of the phenoxy radical could be achieved by a 2,4-pentanediol tethered reaction to give a single diastereomer of Pummerer's ketone analog. By the removal of the chiral auxiliary, the optically active phenoxy radical direct was obtained in good yield.
