208708-96-7Relevant academic research and scientific papers
Macropolyhedral boron-containing cluster chemistry. [PtMe2(PMe2Ph)2] as a cluster metallating agent. Isolation and characterisation of nineteen-vertex [(PMe2Ph)HPt-η4-syn-B18H 19(PMe2Ph)] and eighteen-vertex [(PMe2Ph)2PtS2B15H 14(NHCOMe]
Kaur, Pervinder,Brownless, Annette,Perera, Sarath D.,Cooke, Paul A.,Jelinek, Tomas,Kennedy, John D.,Stibr, Bohumil,Thornton-Pett, Mark
, p. 181 - 185 (1998)
[PtMe2(PMe2Ph)2] reacts quantitatively with [nido-B10H14], [arachno-4-SB8H12] and [nido-7-SB10H12] to give [(PMe2Ph)2PtB10H12], [(PMe2Ph)2PtSB8H10] and [(PMe2Ph)2PtSB10H10]. With [syn-B18H22] it gives nineteen-vertex [(PMe2Ph)HPt-η4-syn-B18H 19(PMe2Ph)]1 and only smaller amounts of [(PMe2Ph)2Pt-η4-syn-B18H 20], whereas with [(anti)-9,9′-S2B16H16] a complex product mixture is generated from which eighteen-vertex [(PMe2Ph)2PtS2B15H 14(NHCOMe)]1 is isolatable after treatment with MeCN in air.
