2089016-10-2

Usage

Uses

Used in Coordination Polymers and Metal-Organic Frameworks:
PZTBA is utilized as a ligand in the formation of coordination polymers and metal-organic frameworks, providing a structural foundation for these materials. Its ability to bind with metal ions allows for the creation of complex and functional materials with potential applications in various industries.
Used in Gas Storage Applications:
PZTBA is employed in the development of materials for gas storage due to its potential to form porous structures. These structures can effectively capture and store gases, making PZTBA a valuable component in the design of materials for gas storage solutions.
Used in Catalysis:
PZTBA is used as a component in catalytic systems, where its ability to bind with metal ions can enhance the catalytic activity of the material. This property makes PZTBA a promising candidate for the development of catalysts in various chemical reactions.
Used in Drug Delivery Systems:
PZTBA is utilized in the design of drug delivery systems, where its unique structure and properties can be harnessed to improve the efficiency and targeting of drug delivery. Its potential to form coordination polymers and metal-organic frameworks can contribute to the development of advanced drug delivery systems with enhanced performance.

Upstream product

• 40742-02-7 dimethyl 4,4′-(1-hydroxy-2-oxoethane-1,2-diyl)dibenzoate 
• 1571-08-0 methyl 4-formylbenzoate 

Relevant academic research and scientific papers

Multifunctional Zinc Metal-Organic Framework Based on Designed H4TCPP Ligand with Aggregation-Induced Emission Effect: CO2 Adsorption, Luminescence, and Sensing Property

A new rigid and symmetrical tetracarboxylic ligand 2,3,5,6-tetrakis(4-carboxyphenyl)pyrazine (H4TCPP) with aggregation-induced emission effect has been designed and synthesized. By using such a ligand, a novel multifunctional metal-organic framework Zn-TCPP has been successfully constructed. The cross-linkage of dinuclear Zn2(COO)4 clusters and organic TCPP4- ligands results in the three-dimensional channel structure of Zn-TCPP, which has a four connected lvt topology with the point symbol of {42.84}. Zn-TCPP not only displays bright blue luminescence arising from the matrix coordination-induced emission effect of the TCPP4- ligand, but also exhibits effective detection for picric acid and Fe3+ ions. In addition, the activated Zn-TCPP possesses a highly porous framework with a Brunauer-Emmett-Teller surface area of 984 m2 g-1 and CO2 adsorption capacity up to 135 cm3 g-1 at 273 K and 732 mmHg. This work represents a successful example of constructing metal-organic frameworks with desired functions based on the designed organic ligand.

Fabrication of (4, 10) and (4, 12)-Connected Multifunctional Zirconium Metal-Organic Frameworks for the Targeted Adsorption of a Guest Molecule

Following the principle of a topology guide, a zirconium MOF (PCN-207) based on the H4TPTA ligand (tetramethyl(4,4′,4″,4?-(pyrazine-2,3,5,6-tetrayl))tetrabenzoic acid) with C2 symmetry and an 8-connected Zr6(μ3-

Rotation Restricted Emission and Antenna Effect in Single Metal-Organic Frameworks

Aggregation induced-emission (AIE) and antenna effects are important luminescence behaviors. Thus, investigating their emission mechanisms and revealing their behaviors have become critical but challenging. Here we design and prepare metal-organic framewo

Ultrastable Zirconium-Based Cationic Metal-Organic Frameworks for Perrhenate Removal from Wastewater

The effective removal of radioactive 99TcO4- anion from nuclear wastewater remains a very difficult unsolved problem. Functional adsorbent materials with high stability, anion-exchange capacity, excellent selectivity, and recyclability are much needed to solve this problem. In this work, we designed two stable cationic metal-organic frameworks (MOFs) - Zr-tcbp-Me and Zr-tcpp-Me - for possible use as adsorbent materials to remove 99TcO4-. Both compounds were synthesized by solvothermal reactions of the tetracarboxylate ligand with zirconium salt, followed by postsynthetic modification (N-methylation). The crystallinity of both zirconium-based MOFs can be well retained under harsh conditions, and they exhibit high adsorption capacity and selectivity toward ReO4- anion, a nonradioactive analogue of 99TcO4-. Zr-tcbp-Me and Zr-tcpp-Me demonstrate the highest framework stability toward acidity among all previously reported cationic MOFs that have been tested for perrhenate removal from wastewater.

Cr2O72-inside Zr/Hf-based metal-organic frameworks: Highly sensitive and selective detection and crystallographic evidence

Herein, we report the synthesis of three pairs of isostructural zirconium- and hafnium-based homometallic metal-organic frameworks (MOFs, termed Zr-MOF-1 and Hf-MOF-1, Zr-MOF-2 and Hf-MOF-2, and Zr-MOF-3 and Hf-MOF-3) with respective scu, sqc, and flu top

Tetrakis(Oxadiazolylphenyl)pyrazines: New st. Andrew’s cross-shaped liquid crystals

π-Conjugated molecules with the shape of St. Andrew’s cross have been synthesized via fourfold Huisgen reaction. Four 2,5- diaryl-1,3,4-oxadiazol arms are attached to a central pyrazine nucleus. These fluorescent stars, when decorated with a rim of eight alkoxy side chains are discotic liquid crystals. Depending on the substitution pattern, the width of the liquid phase varies within a broad range of 25°C to 250°C. In their liquid crystalline phase, the molecules assemble in a typical hexagonal columnar supramolecular arrangement.

STA-27, a porous Lewis acidic scandium MOF with an unexpected topology type prepared with 2,3,5,6-tetrakis(4-carboxyphenyl)pyrazine

A porous scandium MOF denoted STA-27 (St Andrews Porous Material-27) has been synthesised solvothermally using the 2,3,5,6-tetrakis(4-carboxyphenyl)pyrazine anion (TCPP4-) as the tetratopic carboxylate linker. STA-27 possesses a unique scandium-based 1D rod secondary building unit (SBU) comprising corner-sharing scandium Sc2O11 dimers connected via carboxylate groups from the linker. After activation under mild conditions STA-27 is an active Lewis acidic catalyst, while heating at elevated temperatures results in rupturing of the Sc-O-Sc linkages and a phase transition to a different topological type. Under similar synthesis conditions the smaller Al3+ and Ga3+ cations give isostructural MOFs with a different, previously reported, topology type based on chains of corner-sharing MO4(OH)2 octahedra: the Al-form possesses attractive properties for CO2 adsorption.

A multifunctional Zr(iv)-based metal-organic framework for highly efficient elimination of Cr(vi) from the aqueous phase

A highly stable luminescent Zr(iv)-MOF, [Zr6O4(OH)8(H2O)4(TCPP)4]·9DMF·3.5H2O (JLU-MOF60, H4TCPP = 2,3,5,6-tetrakis(4-carboxyphenyl)pyrazine, DMF = N,N-dimethylformami

Tetrakis(oxadiazolylphenyl)pyrazines: New St. Andrew′s Cross-Shaped Liquid Crystals

π-Conjugated molecules with the shape of St. Andrew′s cross have been synthesized via fourfold Huisgen reaction. Four 2,5-diaryl-1,3,4-oxadiazol arms are attached to a central pyrazine nucleus. These fluorescent stars, when decorated with a rim of eight alkoxy side chains are discotic liquid crystals. Depending on the substitution pattern, the width of the liquid phase varies within a broad range of 25 °C to 250 °C. In their liquid crystalline phase, the molecules assemble in a typical hexagonal columnar supramolecular arrangement.