208944-60-9Relevant academic research and scientific papers
Highly diastereoselective synthesis of bicyclo-[3.2.1]octenones through phosphine-mediated condensations of 1,4-dien-3-ones
McDougal, Nolan T.,Schaus, Scott E.
, p. 3117 - 3119 (2007/10/03)
(Chemical Equation Presented) Making rings: A highly diastereoselective synthesis of bicyclo[3.2.1]octenones from 1,4-dien-3-ones occurs through a domino phosphine-mediated formal [4+2] cycloaddition followed by an intramolecular Wittig olefination.
Selective conjugate alkylation of alkyllithium nucleophiles to α, β, γ, δ-unsaturated aldehydes with functionalized Lewis acid receptors
Ooi, Takashi,Kondo, Yuichiro,Kon-i, Kana,Maruoka, Keiji
, p. 403 - 404 (2007/10/03)
Selective 1,4- and 1,6-addition of alkyllithium reagents to α,β,γ,δ-unsaturated aldehydes has been successfully realized with fluorinated aluminum tris(2,6-diphenylphenoxide) (ATPH) derivatives as functionalized Lewis acid receptors.
