208999-51-3

Basic information

• Product Name: (+/-)-(E)-3,7-dimethyl-2-ethoxy-7-[2-(5-methyl)furyl]-1-phenylsulfenyl-3-phenylsulfonyl-1-octene
• Synonyms: (+/-)-(E)-3,7-dimethyl-2-ethoxy-7-[2-(5-methyl)furyl]-1-phenylsulfenyl-3-phenylsulfonyl-1-octene
• CAS NO: 208999-51-3
• Molecular Weight: 512.734
• Mol File: 208999-51-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (+/-)-(E)-3,7-dimethyl-2-ethoxy-7-[2-(5-methyl)furyl]-1-phenylsulfenyl-3-phenylsulfonyl-1-octene(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-(E)-3,7-dimethyl-2-ethoxy-7-[2-(5-methyl)furyl]-1-phenylsulfenyl-3-phenylsulfonyl-1-octene(208999-51-3)
• EPA Substance Registry System: (+/-)-(E)-3,7-dimethyl-2-ethoxy-7-[2-(5-methyl)furyl]-1-phenylsulfenyl-3-phenylsulfonyl-1-octene(208999-51-3)

Safety Data

• Hazardous Substances Data: 208999-51-3(Hazardous Substances Data)

Upstream product

• 38576-60-2 senecioyl cyanide 
• 5651-88-7 phenyl propargyl sulfide 
• 2525-40-8 prop-2-ynylsulfonylbenzene 
• 145917-04-0 3-(2-(5-methylfuryl))-3-methyl-1-butanol 
• 125254-39-9 methyl 3-methyl-3-(5-methylfuran-2-yl)butanoate 
• 145917-19-7 3-[2-(5-methylfurfuryl)]-3-methyl-1-butyl-p-toluenesulfonate 
• 662151-56-6 (2-ethoxy-prop-2-ene-1-sulfonyl)-benzene 
• 662151-43-1 4-[2-(5-methylfurfuryl)]-4-methylpentanenitrile 
• 662151-65-7 4-[2-(5-methyl)furyl]-4-methylpentanol 
• 125254-49-1 4-methyl-4-(5-methylfuran-2-yl)pentanoic acid 
• 108-98-5 thiophenol 
• 208999-45-5 4-[2-(5-methyl)furyl]-4-methylpentyl iodide 
• 541-47-9 3-Methylbutenoic acid 

Downstream Products

• 6892-80-4 (+/-)-widdrol 

Relevant articles and documents

Intramolecular 4+3 cycloadditions. Allylic sulfones as precursors to vinylthionium ions

Treatment of a THF solution of (E)-3 with n-BuLl followed by quenching with an electrophile generally results in regioselective alkylation alpha to the sulfone with the alkene possessing (E) stereochemistry in the major product. High selectivity for the (E) alkylation product can be achieved in the presence of small amounts of HMPA. When those (E) alkylation products possessing a diene moiety in the side chain are treated with Lewis acids, 4+3 cycloaddition products are formed in good to excellent yields.