20908-55-8Relevant academic research and scientific papers
15N and 13C NMR studies on cyclopalladated complexes. Synthetic palladium cyanide chemistry leading to organic nitriles
Affolter, Samuel,Pregosin, Paul S.
, p. 197 - 204 (1990)
15N NMR spectroscopy has been used to determine whether the 15NO group is coordinated in the cyclopalladated nitrosoamine complex 2, PdCl and K2, 11, as well as in several platinum
METAL-ASSISTED REACTIONS-PART 11 RAPID REDUCTION OF N-NITROSOAMINES TO N,N-DISUBSTITUTED HYDRAZINES; THE UTILITY OF SOME LOW-VALENT TITANIUM REAGENTS
Entwistle, Ian D.,Johnstone, A. W.,Wilby, Anna H.
, p. 419 - 423 (2007/10/02)
The rapid reduction of N-nitrosoamines to N,N-disubstituted hydrazines by a low-valent titanium reagent is described.The reagent is selective in that many other functional groups are unaffected by it.The nature of the low-valent titanium reagent is discussed in terms of experimental results of comparisons of its reactivity and that of other low-valent titanium reducing agents.
