209113-69-9

Basic information

• Product Name: 6-O-(2,3-di-O-acetyl-5-O-benzyl-β-D-erythro-apiofuranosyl)-2,3,4-tri-O-benzoyl-α-D-glucopyranosyl trichloroacetimidate
• Synonyms: 6-O-(2,3-di-O-acetyl-5-O-benzyl-β-D-erythro-apiofuranosyl)-2,3,4-tri-O-benzoyl-α-D-glucopyranosyl trichloroacetimidate
• CAS NO: 209113-69-9
• Molecular Weight: 943.185
• Mol File: 209113-69-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 6-O-(2,3-di-O-acetyl-5-O-benzyl-β-D-erythro-apiofuranosyl)-2,3,4-tri-O-benzoyl-α-D-glucopyranosyl trichloroacetimidate(CAS DataBase Reference)
• NIST Chemistry Reference: 6-O-(2,3-di-O-acetyl-5-O-benzyl-β-D-erythro-apiofuranosyl)-2,3,4-tri-O-benzoyl-α-D-glucopyranosyl trichloroacetimidate(209113-69-9)
• EPA Substance Registry System: 6-O-(2,3-di-O-acetyl-5-O-benzyl-β-D-erythro-apiofuranosyl)-2,3,4-tri-O-benzoyl-α-D-glucopyranosyl trichloroacetimidate(209113-69-9)

Safety Data

• Hazardous Substances Data: 209113-69-9(Hazardous Substances Data)

Upstream product

• 545-06-2 trichloroacetonitrile 
• 209113-60-0 ethyl 2,3-di-O-acetyl-3-C-(benzyloxymethyl)-1-thio-α/β-D-erythrofuranoside 
• 35784-51-1 ethyl 2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside 
• 245432-69-3 1,2,3-tri-O-acetyl-3-C-(benzyloxymethyl)-α/β-D-erythrofuranoside 
• 209113-61-1 ethyl 6-O-(2,3-di-O-acetyl-5-O-benzyl-β-D-erythro-apiofuranosyl)-2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside 

Downstream Products

• 209113-73-5 3,4,5-trimethoxyphenyl 2,3,4-tri-O-phenoxyacetyl-6-O-(2,3-di-O-phenoxyacetyl-5-O-benzyl-β-D-erythro-apiofuranosyl)-β-D-glucopyranoside 
• 209113-72-4 3,4,5-trimethoxyphenyl 6-O-(5-O-benzyl-β-D-erythro-apiofuranosyl)-β-D-glucopyranoside 
• 209113-74-6 3,4,5-trimethoxyphenyl 2,3,4-tri-O-phenoxyacetyl-6-O-(2,3-di-O-phenoxyacetyl-β-D-erythro-apiofuranosyl)-β-D-glucopyranoside 
• 209113-70-2 3,4,5-trimethoxyphenyl 6-O-(2,3-di-O-acetyl-5-O-benzyl-β-D-erythro-apiofuranosyl)-2,3,4-tri-O-benzoyl-β-D-glucopyranoside 

Relevant articles and documents

Synthesis of 3,4,5-trimethoxyphenyl 5-O-caffeoyl-β-D-erythro- apiofuranosyl-(1→6)-β D-glucopyranoside: Kelampayoside B

Chemoselective NIS/cat. TfOH-mediated glycosylation of ethyl 2,3,4-tri- O-benzoyl-1-thio-β-D-glucopyranoside (4) with ethyl 2,3-di-O-acetyl-5-O- benzyl-1-thio-β-D-erythro-apiofuranoside (3) gave dimer 5 in an excellent yield. BF3Et2O-catalysed condensation of the α-trichloroacetimidate 18, accessible in two steps from 5, with 3,4,5-trimethoxyphenol gave β-linked derivative 19 which could be transformed in five steps into the title compound.