209125-48-4Relevant academic research and scientific papers
General syntheses of ethyl 2-ulosonates and 3-deoxy-D-manno-oct-2- ulosonic acid from carbohydrate lactones with 1-ethoxyvinyllithium
Jiang, Shende,Rycroft, Anthony D.,Singh, Gurdial,Wang, Xiang-Zhu,Wu, Yu-Lin
, p. 3809 - 3812 (2007/10/03)
Reactions of 1-ethoxyvinyllithium with isopropylidene or benzyl protected sugar lactones afforded the corresponding hemiacetals which, on ozonolysis, gave the ethyl 2-ulosonates. This allowed a rapid and efficient synthesis of 3-deoxy-D-manno-oct-2-ulosonic acrid (KDO).
