209394-99-0Relevant academic research and scientific papers
A triple layered helical chiral cyclophane-one-pot synthesis, enantiomer separation and chiroptical properties
Harren, Joerg,Sobanski, Adam,Nieger, Martin,Yamamoto, Chiyo,Okamoto, Yoshio,Voegtle, Fritz
, p. 1369 - 1375 (1998)
The triple layered tetraazacyclophane 3a was prepared in high yield by a fourfold bond connection in a one-pot reaction sequence. The helical chirality of 3a results from the unique crossed meta/meta-cyclophane linkage. A racemisation process can only tak
