209474-75-9Relevant academic research and scientific papers
Z-selective intramolecular Horner-Wadsworth-Emmons reaction for the synthesis of macrocyclic alkenes
Ando, Kaori,Sato, Kaori
, p. 1284 - 1287 (2011/03/22)
The Z-selective intramolecular Horner-Wadsworth-Emmons reaction of the substrates 7-12 (RO)2P(O)CHR′CO2Et (R′ = (CH2)nCHO) (R = Ph or o-tBuC6H4) gives the 13-18-membered cyclic alkenes selectively (up to Z:E = 97:3) in good yields using NaH in THF under high dilution conditions.
Pheromone synthesis, CXCIV. - Synthesis of the enantiomers of (Z)-21- methyl-8-pentatriacontene, the major component of the female-produced contact sex pheromone of the yellow-spotted longicorn beetle, Psacothea hilaris
Domon, Kenji,Takikawa, Hirosato,Mori, Kenji
, p. 981 - 984 (2007/10/03)
Both the enantiomers of (Z)-21-methyl-8-pentatriacontene (1), the major component of the female-produced contact sex pheromone of the yellow-spotted longicorn beetle (Psacothea hilaris), were synthesized by starting from the enantiomers of citronellol (2).
