209964-99-8Relevant articles and documents
Synthesis, structure, photo- and electroluminescent properties of bis{(4-methyl-N-[2-[(E)-2-pyridyliminomethyl]phenyl)]benzenesulfonamide}zinc(II)
Burlov, Anatolii S.,Mal'tsev, Eugenii I.,Vlasenko, Valery G.,Garnovskii, Dmitrii A.,Dmitriev, Artem V.,Lypenko, Dmitrii A.,Vannikov, Anatoly V.,Dorovatovskii, Pavel V.,Lazarensko, Vladimir A.,Zubavichus, Yan V.,Khrustalev, Victor N.
, p. 231 - 237 (2017)
The synthesis, structure and spectroscopic properties of luminescent Zn(II) complex containing 4-methyl-N-[2-[(E)-pyridinylmethyl]phenyl]benzosulfimide ligand are described. The Zn(II) complex was characterized by single-crystal X-ray diffraction study. Time-dependent density functional theory calculations at the B3LYP/6-31G? level were performed on Zn(II) complex to interpretation its experimental UV–Vis absorption spectrum. OLED device with Zn(II) complex as light-emitting layer has been fabricated. The electroluminescent spectrum of OLED showed a dominant yellow emission at 525?nm (Commission Internationale de l'eclairage (CIE) coordinates x?=?0.409 and y?=?0.506) and a weak shoulder at 650?nm without any other distinguishing emission from host or adjacent layers. The fabricated OLED generated luminance of more than 1000?cd/m2 at 16?V, current density 600?mA/cm2 and rather low turn-on voltage of ca. 4?V and power efficiency 1?lm/W.
Electrochemical synthesis of metal (II) complexes of Schiff base 2-tosylamino (2′-pyridyl)aniline: The crystal structure of bis-[2-tosylamino(2′-pyridyl)anilinato]cobalt(II)
Garcia-Vazquez, Jose A.,Romero, Jaime,Duran, Maria L.,Sousa, Antonio,Garnovskii, Alexander D.,Burlov, Anatolii S.,Garnovskii, Dimitrii A.
, p. 1547 - 1552 (2008/10/09)
Complexes of cobalt(II), nickel(II), copper(II), zinc(II) and cadmium(II) with the anion of the Schiff base 2-tosylamino(2′-pyridyl)aniline (HL) have been prepared by using an electrochemical procedure. These compounds were characterized by elemental analysis, IR, UV and NMR spectroscopy, and in the case of [CoL2] by X-ray diffraction methods. In this compound the cobalt(II) atom is in a distorted tetrahedral environment, each Schiff base anion acting as a bidentate ligand with the pyridine nitrogen atom uncoordinated.
