209965-00-4Relevant academic research and scientific papers
Electrochemical synthesis of metal (II) complexes of Schiff base 2-tosylamino (2′-pyridyl)aniline: The crystal structure of bis-[2-tosylamino(2′-pyridyl)anilinato]cobalt(II)
Garcia-Vazquez, Jose A.,Romero, Jaime,Duran, Maria L.,Sousa, Antonio,Garnovskii, Alexander D.,Burlov, Anatolii S.,Garnovskii, Dimitrii A.
, p. 1547 - 1552 (2008/10/09)
Complexes of cobalt(II), nickel(II), copper(II), zinc(II) and cadmium(II) with the anion of the Schiff base 2-tosylamino(2′-pyridyl)aniline (HL) have been prepared by using an electrochemical procedure. These compounds were characterized by elemental analysis, IR, UV and NMR spectroscopy, and in the case of [CoL2] by X-ray diffraction methods. In this compound the cobalt(II) atom is in a distorted tetrahedral environment, each Schiff base anion acting as a bidentate ligand with the pyridine nitrogen atom uncoordinated.
